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Nevin Manimala Statistics

Steric control of sorting regimes in self-assembled cages

Chem Commun (Camb). 2021 Nov 10. doi: 10.1039/d1cc05610g. Online ahead of print.

ABSTRACT

Control of self-sorting regimes is achieved through adjustment of steric interactions in self-assembled coordination cages. The self-assembly regime of dynamic mixtures of heteroleptic cages is followed by HPLC to show that statistical or biased distributions can be selectively obtained, including isolation of a single heteroleptic species.

PMID:34755718 | DOI:10.1039/d1cc05610g

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