Na(4)Ga(8)S(14): a Ga-enriched wide band gap ternary alkali-metal sulfide with unique [Ga(12)S(42)] 12-membered rings

Dalton Trans. 2022 Mar 9. doi: 10.1039/d2dt00295g. Online ahead of print.

ABSTRACT

A Ga-enriched ternary alkali-metal sulfide Na₄Ga₈S₁₄ has been synthesized by a high temperature solid-state reaction. It crystallizes in the centrosymmetric Pbca (no. 61) space group with cell parameters a = 13.5260(4) Å, b = 11.4979(3) Å, c = 29.9592(9) Å, and Z = 8, and exhibits a three-dimensional (3D) network structure constructed from unique [Ga₁₂S₄₂] 12-membered rings, one-dimensional _∞[Ga₄S₁₁] chains, individual [GaS₄] units and Na⁺ ions. The experimental band gap of Na₄Ga₈S₁₄ was measured as ∼3.57 eV. Theoretical calculations indicate that the title compound is a direct band gap compound and the band gap is mainly determined by [GaS₄] units. Meanwhile, statistical analysis shows that the atomic ratio N (N = A^IA^II/Ga, where A^I = alkali-metal, A^II = alkaline earth-metal) can be used to regulate the connection of [GaS₄] units from zero-dimensional (0D) isolated groups, one-dimensional (1D) chains, and two-dimensional (2D) layers to 3D frameworks in Ga-containing alkali- and/or alkaline earth-metal chalcogenides. The results enrich the diversity of alkali-metal sulfides and give an insight into the structural regulation of alkali- and/or alkaline earth-metal chalcogenides.

PMID:35262155 | DOI:10.1039/d2dt00295g