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Amine-modified polyionic liquid supports enhance the efficacy of PdNPs for the catalytic hydrogenation of CO2 to formate

Chem Commun (Camb). 2023 Oct 25. doi: 10.1039/d3cc04987f. Online ahead of print.

ABSTRACT

Palladium nanoparticles stabilised by aniline modified polymer immobilised ionic liquid is a remarkably active catalyst for the hydrogenation of CO2 to formate; the initial TOF of 500 h-1 is markedly higher than either unmodified catalyst or its benzylamine and N,N-dimethylaniline modified counterparts and is among the highest to be reported for a PdNP-based catalyst.

PMID:37877311 | DOI:10.1039/d3cc04987f

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